Novel Complexes of isothiosemicarbazone with MoO2 moiety
سال
: 2013
چکیده: We report 4-methoxysalicylaldhyde S-allyl isothiosemicarbazone (HL) and its Mo(VI) complexes, [ML]. The crystal structure analysis indicates that the metal has six-coordinate distorted octahedral geometry. All experimental results confirmed that HL is a tridentate mono-deprotonated ligand (NNO), coordinating through phenolic oxygen, azomethine nitrogen, and isothioamide nitrogen. MoO2 bond lengths and angles are 1.701(12)-1.719(11) Å and 104.30(7)-105.44(6)˚, respectively. The distances of Mo1-O5 (2.321(1) Å) and Mo1-N4 (2.345(14) Å) for Mo(VI) complexes, are the longest in the coordination sphere of Mo.
کلیدواژه(گان): Isothiosemicarbazone,Molybdenum(VI) complex,Spectroscopy,Crystal structure
کالکشن
:
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آمار بازدید
Novel Complexes of isothiosemicarbazone with MoO2 moiety
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| contributor author | میلاد محجوبی زاده | en |
| contributor author | رضا تکجو چلارس | en |
| contributor author | milad mahjoobizadeh | fa |
| contributor author | Reza Takjoo | fa |
| date accessioned | 2020-06-06T14:10:59Z | |
| date available | 2020-06-06T14:10:59Z | |
| date copyright | 9/3/2013 | |
| date issued | 2013 | |
| identifier uri | https://libsearch.um.ac.ir:443/fum/handle/fum/3385899 | |
| description abstract | We report 4-methoxysalicylaldhyde S-allyl isothiosemicarbazone (HL) and its Mo(VI) complexes, [ML]. The crystal structure analysis indicates that the metal has six-coordinate distorted octahedral geometry. All experimental results confirmed that HL is a tridentate mono-deprotonated ligand (NNO), coordinating through phenolic oxygen, azomethine nitrogen, and isothioamide nitrogen. MoO2 bond lengths and angles are 1.701(12)-1.719(11) Å and 104.30(7)-105.44(6)˚, respectively. The distances of Mo1-O5 (2.321(1) Å) and Mo1-N4 (2.345(14) Å) for Mo(VI) complexes, are the longest in the coordination sphere of Mo. | en |
| language | English | |
| title | Novel Complexes of isothiosemicarbazone with MoO2 moiety | en |
| type | Conference Paper | |
| contenttype | External Fulltext | |
| subject keywords | Isothiosemicarbazone | en |
| subject keywords | Molybdenum(VI) complex | en |
| subject keywords | Spectroscopy | en |
| subject keywords | Crystal structure | en |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1036164.html | |
| conference title | پانزدهمین سمینار شیمی معدنی ایران | fa |
| identifier articleid | 1036164 |