Novel Complexes of isothiosemicarbazone with MoO2 moiety

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Year

: 2013

Abstract: We report 4-methoxysalicylaldhyde S-allyl isothiosemicarbazone (HL) and its Mo(VI) complexes, [ML]. The crystal structure analysis indicates that the metal has six-coordinate distorted octahedral geometry. All experimental results confirmed that HL is a tridentate mono-deprotonated ligand (NNO), coordinating through phenolic oxygen, azomethine nitrogen, and isothioamide nitrogen. MoO2 bond lengths and angles are 1.701(12)-1.719(11) Å and 104.30(7)-105.44(6)˚, respectively. The distances of Mo1-O5 (2.321(1) Å) and Mo1-N4 (2.345(14) Å) for Mo(VI) complexes, are the longest in the coordination sphere of Mo.

URI: https://libsearch.um.ac.ir:443/fum/handle/fum/3385899

Keyword(s): Isothiosemicarbazone,Molybdenum(VI) complex,Spectroscopy,Crystal structure

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Novel Complexes of isothiosemicarbazone with MoO2 moiety

contributor author	میلاد محجوبی زاده	en
contributor author	رضا تکجو چلارس	en
contributor author	milad mahjoobizadeh	fa
contributor author	Reza Takjoo	fa
date accessioned	2020-06-06T14:10:59Z
date available	2020-06-06T14:10:59Z
date copyright	9/3/2013
date issued	2013
identifier uri	https://libsearch.um.ac.ir:443/fum/handle/fum/3385899?locale-attribute=en
description abstract	We report 4-methoxysalicylaldhyde S-allyl isothiosemicarbazone (HL) and its Mo(VI) complexes, [ML]. The crystal structure analysis indicates that the metal has six-coordinate distorted octahedral geometry. All experimental results confirmed that HL is a tridentate mono-deprotonated ligand (NNO), coordinating through phenolic oxygen, azomethine nitrogen, and isothioamide nitrogen. MoO2 bond lengths and angles are 1.701(12)-1.719(11) Å and 104.30(7)-105.44(6)˚, respectively. The distances of Mo1-O5 (2.321(1) Å) and Mo1-N4 (2.345(14) Å) for Mo(VI) complexes, are the longest in the coordination sphere of Mo.	en
language	English
title	Novel Complexes of isothiosemicarbazone with MoO2 moiety	en
type	Conference Paper
contenttype	External Fulltext
subject keywords	Isothiosemicarbazone	en
subject keywords	Molybdenum(VI) complex	en
subject keywords	Spectroscopy	en
subject keywords	Crystal structure	en
identifier link	https://profdoc.um.ac.ir/paper-abstract-1036164.html
conference title	پانزدهمین سمینار شیمی معدنی ایران	fa
identifier articleid	1036164