Conductometric study of complexation reaction between benzylbisthiosemicarbazon and Ni2+, CO2+, Zn2+ and Cr3+ metal cations in pure and binary mixed non-aqueous solvents
نویسنده:
, , , , , ,سال
: 2013
چکیده: We have investigated the complexation reactions of benzylbisthiosemicarbazon (BTC) with Ni2+, CO2+, Zn2+ and Cr3+ cations at different temperatures in
acetonitrile-dimethylformamide (AN-DMF) binary non-aqueous solvent solutions using electrical conductometry method.The values of formation constants
of the complexes were determined from computer fitting of the conductance versus mole ratio data using a GENPLOT computer programme[1].BTC forms
1:1 complexes with the studied metal cations in solutions. In most cases, a non-linear relationship is observed between the stability constants of the
complexes ( ) and the composition of the AN-DMF binary solvent.
acetonitrile-dimethylformamide (AN-DMF) binary non-aqueous solvent solutions using electrical conductometry method.The values of formation constants
of the complexes were determined from computer fitting of the conductance versus mole ratio data using a GENPLOT computer programme[1].BTC forms
1:1 complexes with the studied metal cations in solutions. In most cases, a non-linear relationship is observed between the stability constants of the
complexes ( ) and the composition of the AN-DMF binary solvent.
کلیدواژه(گان): BTC,Conductometery
کالکشن
:
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آمار بازدید
Conductometric study of complexation reaction between benzylbisthiosemicarbazon and Ni2+, CO2+, Zn2+ and Cr3+ metal cations in pure and binary mixed non-aqueous solvents
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| contributor author | حمیده شریفی نوقابی | en |
| contributor author | غلامحسین رونقی | en |
| contributor author | محمدحسین ارباب زوار | en |
| contributor author | J. Ebrahimi | en |
| contributor author | Hamideh Sharifi Noghabi | fa |
| contributor author | Glamhossein Ronagi | fa |
| contributor author | Mohammad Hossein Arbab Zavar | fa |
| date accessioned | 2020-06-06T14:09:30Z | |
| date available | 2020-06-06T14:09:30Z | |
| date copyright | 2/26/2013 | |
| date issued | 2013 | |
| identifier uri | https://libsearch.um.ac.ir:443/fum/handle/fum/3384832 | |
| description abstract | We have investigated the complexation reactions of benzylbisthiosemicarbazon (BTC) with Ni2+, CO2+, Zn2+ and Cr3+ cations at different temperatures in acetonitrile-dimethylformamide (AN-DMF) binary non-aqueous solvent solutions using electrical conductometry method.The values of formation constants of the complexes were determined from computer fitting of the conductance versus mole ratio data using a GENPLOT computer programme[1].BTC forms 1:1 complexes with the studied metal cations in solutions. In most cases, a non-linear relationship is observed between the stability constants of the complexes ( ) and the composition of the AN-DMF binary solvent. | en |
| language | English | |
| title | Conductometric study of complexation reaction between benzylbisthiosemicarbazon and Ni2+, CO2+, Zn2+ and Cr3+ metal cations in pure and binary mixed non-aqueous solvents | en |
| type | Conference Paper | |
| contenttype | External Fulltext | |
| subject keywords | BTC | en |
| subject keywords | Conductometery | en |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1033664.html | |
| conference title | نوزدهمین سمینار شیمی تجزیه ایران | fa |
| conference location | مشهد | fa |
| identifier articleid | 1033664 |