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RISSynthesis, X-ray structure, spectroscopic properties and DFT studies of some dithiocarbazate complexes of nickel(II)
Two nickel(II) complexes with formulae NiL2 (1) and NiL’Im (2) (HL = allyl 2-benzylidene-hydrazinecarbodithioate, H2L0 = allyl 2-(2-hydroxybenzylidene)hydrazinecarbodithioate, Im = Imidazole) have been synthesized and ...
Dioxidouranium isothiosemicarbazone coordination compounds: synthesis, characterization, crystal structure, and thermal behavior
Five uranium complexes with UO2L′(solv) formula (L′: prepared by condensation reaction between 2-hydroxyacetophenon S-pentyl isothiosemicarbazone (H2L) and 5-bromosalicylaldehyde (Sal); solv: ethanol (1), 2-propanol (2), ...
سنتز و شناسایی کمپلکسهای جدید از برخی عناصر واسطه با لیگاند 4-(2-هیدروکسی اتیل)-1-(تیوفن-2-ایل متیلن) هیدرازین کربوتیوآمید
چکیده
،(4) Pd(HL)2،(3) Zn(HL)Cl2،(2)Zn(L)2،(1) Cu(L) برخی از کمپلکس های فلزات واسطه همچون 2
- -2 هیدروکسی اتیل)- 1-(تیوفن- 2 )-4-، NS 7) با لیگاند دودندانه ) Cd(HL)I 6)و 2 ) Cd(HL)Cl2 ،(5)Cd(L)2
،13C ...
Two new Ni(II) and Mo(VI) Schiff base complexes: synthesis, Xray structure and DFT calculation
-In recent decades aromatic Schiff base compounds have been attract more attention due to useful properties in such as anticancer, antimicrobial and many other useful properties in various filed. It is considerable that ...
Cu(II) and V(IV) complexes of new tridentate ONO Schiff base: Synthesis, structure, TGA and DFT calculations
In recent decades many research show the complexes contain aromatic heterocyclic ring such as bipyridine and phenanthroline as a good metallointercalators tend to connect to DNA [1, 2]. The ability of vanadium and copper ...
Novel Complexes of isothiosemicarbazone with MoO2 moiety
We report 4-methoxysalicylaldhyde S-allyl isothiosemicarbazone (HL) and its Mo(VI) complexes, [ML]. The crystal structure analysis indicates that the metal has six-coordinate distorted octahedral geometry. All experimental ...
Iron(III) and copper(II) complexes with thiosemicarbazide-based ligand
Thiosemicarbazon derivations and their complexes have been attracting attention of the researchers, not only because of their interesting coordination chemistry, but also because of the biological properties [1-3]. New ...