Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source
نویسنده:
, , , , , , ,سال
: 2018
چکیده: Attempted heterocyclization of 5-bromo-2,4-diamino-6-substituted pyrimidines in a mixture of DMF and trialkylamines (Et3N or N,N-diisopropylethylamine) under mild conditions, led to the formation of new dehalogenated derivatives as the main product. This metal-free catalyzed debromination process presents DMF/R3N combination as a potential metal-free reductive system.
کلیدواژه(گان): Metal-Free Debromination,5-Bromopyrimidine,Hydrogen Source
کالکشن
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آمار بازدید
Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source
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contributor author | سیده مهسا موسوی | en |
contributor author | مهدی بکاولی | en |
contributor author | علی شیری | en |
contributor author | جواد تاج آبادی | en |
contributor author | Mahsa Mousavi | fa |
contributor author | Mehdi Bakavoli | fa |
contributor author | Ali Shiri | fa |
contributor author | javad tajabadi | fa |
date accessioned | 2020-06-06T13:40:40Z | |
date available | 2020-06-06T13:40:40Z | |
date issued | 2018 | |
identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3364672 | |
description abstract | Attempted heterocyclization of 5-bromo-2,4-diamino-6-substituted pyrimidines in a mixture of DMF and trialkylamines (Et3N or N,N-diisopropylethylamine) under mild conditions, led to the formation of new dehalogenated derivatives as the main product. This metal-free catalyzed debromination process presents DMF/R3N combination as a potential metal-free reductive system. | en |
language | English | |
title | Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source | en |
type | Journal Paper | |
contenttype | External Fulltext | |
subject keywords | Metal-Free Debromination | en |
subject keywords | 5-Bromopyrimidine | en |
subject keywords | Hydrogen Source | en |
journal title | ChemistrySelect | fa |
pages | 5401-5404 | |
journal volume | 3 | |
journal issue | 19 | |
identifier link | https://profdoc.um.ac.ir/paper-abstract-1069036.html | |
identifier articleid | 1069036 |