Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source
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, , , , , , ,Year
: 2018
Abstract: Attempted heterocyclization of 5-bromo-2,4-diamino-6-substituted pyrimidines in a mixture of DMF and trialkylamines (Et3N or N,N-diisopropylethylamine) under mild conditions, led to the formation of new dehalogenated derivatives as the main product. This metal-free catalyzed debromination process presents DMF/R3N combination as a potential metal-free reductive system.
Keyword(s): Metal-Free Debromination,5-Bromopyrimidine,Hydrogen Source
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Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source
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| contributor author | سیده مهسا موسوی | en |
| contributor author | مهدی بکاولی | en |
| contributor author | علی شیری | en |
| contributor author | جواد تاج آبادی | en |
| contributor author | Mahsa Mousavi | fa |
| contributor author | Mehdi Bakavoli | fa |
| contributor author | Ali Shiri | fa |
| contributor author | javad tajabadi | fa |
| date accessioned | 2020-06-06T13:40:40Z | |
| date available | 2020-06-06T13:40:40Z | |
| date issued | 2018 | |
| identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3364672?locale-attribute=en | |
| description abstract | Attempted heterocyclization of 5-bromo-2,4-diamino-6-substituted pyrimidines in a mixture of DMF and trialkylamines (Et3N or N,N-diisopropylethylamine) under mild conditions, led to the formation of new dehalogenated derivatives as the main product. This metal-free catalyzed debromination process presents DMF/R3N combination as a potential metal-free reductive system. | en |
| language | English | |
| title | Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | Metal-Free Debromination | en |
| subject keywords | 5-Bromopyrimidine | en |
| subject keywords | Hydrogen Source | en |
| journal title | ChemistrySelect | fa |
| pages | 5401-5404 | |
| journal volume | 3 | |
| journal issue | 19 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1069036.html | |
| identifier articleid | 1069036 |