An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations
Author:
, , , , , , , , , , , ,Year
: 2010
Abstract: Abstract
A unique ionic hybrid material [C6H12N5O]3[(PO4)W12O36] 5H2O has been synthesized from the reaction of ((1H-tetrazole-5-
yl)methyl)morpholine and a-H3[(PO4)W12O36] 21H2O. It has successfully been characterized by elemental analysis, IR and 1H
NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is onstructed from the three [C6H12N5O]+ cations and a-Keggin [(PO4)W12O36]3 polyoxoanion. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/1[(PO4)W12O36]3 ) which forming via van derWaals interactions along the x axis.
A unique ionic hybrid material [C6H12N5O]3[(PO4)W12O36] 5H2O has been synthesized from the reaction of ((1H-tetrazole-5-
yl)methyl)morpholine and a-H3[(PO4)W12O36] 21H2O. It has successfully been characterized by elemental analysis, IR and 1H
NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is onstructed from the three [C6H12N5O]+ cations and a-Keggin [(PO4)W12O36]3 polyoxoanion. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/1[(PO4)W12O36]3 ) which forming via van derWaals interactions along the x axis.
Keyword(s): Polyoxometalate,Inorganic–organic hybrid,Morpholine,Dodecatungstophosphate,Crystal structure
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An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations
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| contributor author | Mohsen Nikpour | en |
| contributor author | M. Nikpour | en |
| contributor author | حسین اشتیاق حسینی | en |
| contributor author | مسعود میرزائی شهرابی | en |
| contributor author | مسعود میرزائی شهرابی | en |
| contributor author | Amir Aghaei Kaju | en |
| contributor author | A. Aghaie Kaju | en |
| contributor author | Ya Guang Chen | en |
| contributor author | Soroush Zarinabadi | en |
| contributor author | S. Zarinabadi | en |
| contributor author | Hossein Eshtiagh Hosseini | fa |
| contributor author | Masoud Mirzaei Shahrabi | fa |
| contributor author | Masoud Mirzaei Shahrabi | fa |
| date accessioned | 2020-06-06T14:18:16Z | |
| date available | 2020-06-06T14:18:16Z | |
| date issued | 2010 | |
| identifier uri | https://libsearch.um.ac.ir:443/fum/handle/fum/3390932?locale-attribute=en | |
| description abstract | Abstract A unique ionic hybrid material [C6H12N5O]3[(PO4)W12O36] 5H2O has been synthesized from the reaction of ((1H-tetrazole-5- yl)methyl)morpholine and a-H3[(PO4)W12O36] 21H2O. It has successfully been characterized by elemental analysis, IR and 1H NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is onstructed from the three [C6H12N5O]+ cations and a-Keggin [(PO4)W12O36]3 polyoxoanion. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/1[(PO4)W12O36]3 ) which forming via van derWaals interactions along the x axis. | en |
| language | English | |
| title | An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | Polyoxometalate | en |
| subject keywords | Inorganic–organic hybrid | en |
| subject keywords | Morpholine | en |
| subject keywords | Dodecatungstophosphate | en |
| subject keywords | Crystal structure | en |
| journal title | Chinese Chemical Letters | fa |
| pages | 501-505 | |
| journal volume | 21 | |
| journal issue | 21 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1014050.html | |
| identifier articleid | 1014050 |