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Single-wall carbon nanotubes synthesized using organic additives to Co-Mo catalysts supported on nanoporous MgO

Author:
علیمراد رشیدی
,
محمد مهدی اکبرنژاد
,
علی اکبر خدادادی
,
یدا... مرتضوی
,
علی احمدپور
,
Ali Ahmadpour
Year
: 2007
Abstract: Carbon nanotubes (CNTs) were synthesized by catalytic decomposition of
20% methane in hydrogen over Co–Mo/MgO catalysts at 1000 ◦C. The
catalysts were prepared by a modified sol–gel method, using sorbitol,
ethylenediamine tetraacetic acid (EDTA), tartaric acid and citric acid as
organic additives. The specific surface area (SSA) of the catalysts changes
with the organic additives in the order of sorbitol > EDTA > citric acid >
tartaric acid. As a result the crystallite size, dispersion of Co–Mo and hence
the quality of the carbon nanotubes change with the organic additive. Up to
180 wt% yield of high quality single-wall carbon nanotubes (SWNTs) with
inner-wall diameter close to 1.0–1.2 nm are obtained on the catalyst prepared
in the presence of sorbitol.
URI: https://libsearch.um.ac.ir:443/fum/handle/fum/3357273
Keyword(s): Carbon nanotubes,catalyst,MgO,Organic additives
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    Single-wall carbon nanotubes synthesized using organic additives to Co-Mo catalysts supported on nanoporous MgO

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contributor authorعلیمراد رشیدیen
contributor authorمحمد مهدی اکبرنژادen
contributor authorعلی اکبر خدادادیen
contributor authorیدا... مرتضویen
contributor authorعلی احمدپورen
contributor authorAli Ahmadpourfa
date accessioned2020-06-06T13:29:47Z
date available2020-06-06T13:29:47Z
date issued2007
identifier urihttps://libsearch.um.ac.ir:443/fum/handle/fum/3357273?locale-attribute=en
description abstractCarbon nanotubes (CNTs) were synthesized by catalytic decomposition of
20% methane in hydrogen over Co–Mo/MgO catalysts at 1000 ◦C. The
catalysts were prepared by a modified sol–gel method, using sorbitol,
ethylenediamine tetraacetic acid (EDTA), tartaric acid and citric acid as
organic additives. The specific surface area (SSA) of the catalysts changes
with the organic additives in the order of sorbitol > EDTA > citric acid >
tartaric acid. As a result the crystallite size, dispersion of Co–Mo and hence
the quality of the carbon nanotubes change with the organic additive. Up to
180 wt% yield of high quality single-wall carbon nanotubes (SWNTs) with
inner-wall diameter close to 1.0–1.2 nm are obtained on the catalyst prepared
in the presence of sorbitol.
en
languageEnglish
titleSingle-wall carbon nanotubes synthesized using organic additives to Co-Mo catalysts supported on nanoporous MgOen
typeJournal Paper
contenttypeExternal Fulltext
subject keywordsCarbon nanotubesen
subject keywordscatalysten
subject keywordsMgOen
subject keywordsOrganic additivesen
journal titleNanotechnologyen
journal titleNanotechnologyfa
journal volume0
journal issue0
identifier linkhttps://profdoc.um.ac.ir/paper-abstract-1004871.html
identifier articleid1004871
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