Search
CSV
RISThe first coordination polymers with an [O]2[N]P(S)-Hg segment: a combined experimental, theoretical and database study
The study of one-dimensional coordination polymers {Hg2Cl4L1}n (1), {HgBr2L1}n (2) and {Hg2Cl4L2}n (3) (L1 = (S)P(OC2H5)2NHC6H4NHP(S)(OC2H5)2 and L2 = (S)P(OC2H5)2NC4H8NP(S)(OC2H5)2) is the first such structural study of ...
A novel tubular hydrogen-bond pattern in a new diazaphosphole oxide: a combination of X-ray crystallography and theoretical study of hydrogen bonds
In the structure of 2-(4-chloroanilino)-1,3,2λ4-diazaphosphol-2-one, C12H11ClN3OP, each molecule is connected with four neighbouring molecules through (N—H)2…O hydrogen bonds. These hydrogen bonds form a tubular arrangement ...
A new solvated thiophosphoramide: single crystal X-ray diffraction, NMR study and Hirshfeld surface analysis
Hirshfeld surfaces and two-dimensional fingerprint plots are used to study short intermolecular contacts in of phosphoramides1and also in organotin (IV)-phosphoramide complexe2. In this study we present the crystal structure ...
The First Coordination Polymers withan [O]2[N]P(S)—HgSegment
During the last two decades, design and synthesis of novel coordination polymers are attracting more attention1. In addition, the coordination chemistry of bidentate ligands has been studied for over thirty years2. The ...
A novel tubular hydrogen bond pattern in the crystal structure of a new diazaphosphole oxide: (4-Cl-C6H4NH)P(O)(1,2-NH)2C6H4
In this work, we report on the synthesis, spectroscopic characterization and X-ray crystal structure determination of a new diazaphosphole oxide, (4-Cl-C6H4NH)P(O)(1,2-NH)2C6H4 namely 2-[para-chloroanilino]-1,3,2λ4-diaza ...
Synthesis, spectral properties and DFT/TD-DFT investigation on the electronic structure of O,O'-diethyl(3,4-dimethylanilin-1-yl) thiophosphonate
The title compound, O,O'-diethyl (3,4-dimethylanilin-1-yl) thiophosphonate, was obtained through the reaction of 3,4-dimethylaniline and P(S)[OC2H5]2Cl at ice-bath temperature, in a procedure similar to what was previously ...