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RISNovel Complexes of isothiosemicarbazone with MoO2 moiety
We report 4-methoxysalicylaldhyde S-allyl isothiosemicarbazone (HL) and its Mo(VI) complexes, [ML]. The crystal structure analysis indicates that the metal has six-coordinate distorted octahedral geometry. All experimental ...
Iron(III) and copper(II) complexes with thiosemicarbazide-based ligand
Thiosemicarbazon derivations and their complexes have been attracting attention of the researchers, not only because of their interesting coordination chemistry, but also because of the biological properties [1-3]. New ...
Copper(II) complex by 1,10-phenanthroline and Salicylaldehyde S-benzylisothiosemicarbazone hydrogen chloride: Synthesis, characterization and crystal structure
Mixed-ligand Cu(II) complex with general formula of [Cu(Phen)2Cl].H2L,Cl,H2O (Figure) is prepared by reaction of Cu(OAc)2.H2O, 1,10-phenanthroline and salicylaldehyde S-benzylisothiosemicarbazone.hydrogenchloride (H2L) in ...
سنتز، بررسی ساختار بلوری-مولکولی و طیفی کمپلکس لیگاند-مخلوط جدید از مس(II) با لیگاند دو دندانه 1و10-فنانترولین به همراه سالیسیل آلدهید S-بنزیل ایزوتیوسمی کربازون
کمپلکس لیگاند-مخلوط مس(II) از واکنش لیگاند سالیسیل آلدهید S-بنزیل ایزوتیوسمی کربازون.هیدروژن کلرید (H2L)، نمک مس(II) استات.تک آبه و 1و10-فنانترولین (Phen) با فرمول عمومی [Cu(Phen)2Cl].H2L,Cl,H2O تهیه شد. ساختار آن به وسیله ...
Crystal growth and intramolecular hydrogen bond effects on activity of a novel Schiff base ligand: An experimental and theoretical approach
Reaction of thiosemicarbazide with alkyl halides produce isothiosemicarbazides which in condensation reactions with aldehydes or ketones could yield isothiosemicarbazones. A new tridentate Schiff base compound, salicylaldehyde ...
Decaaquabis(μ3-4-hydroxypyridine-2,6-dicarboxylato)bis(4-hydroxypyridine-2,6-dicarboxylato)tetramanganese(II) 3.34-hydrate: a new three-dimensional open metal-organic framework based on a tetranuclear MnII complex of chelidamic acid and undecameric stitch
In this paper, the new [Mn~4~(cdaH)~4~^.^10H~2~O]^.^3.34H~2~O complex
between Mn(II) and 4-Hydroxyoyridine-2,6-dicarboxylic acid
(chelidamic acid, cdaH~3~) is described. It features tetranuclear
Mn(II) ...
Two novel mononuclear and binuclear complexes of Ni(II) and Ca(II) atoms containing 4-hydroxy-pyridine-2,6-dicarboxylic acid, 2-aminopyrimidine, and2,4,6-triamino-1,3,5-triazine ligands: Synthesis, X-ray crystal structure andthermal property
The reactions of the 4-hydroxy-pyridine-2,6-dicarboxylic acid (for short
H3hypydc), 2-aminopyrimidine (for short 2-apym), and 2,4,6-triamino-1,3,5-
triazine (for short tata) with nickel(II) chloride and ...
Binuclear complex of Cu(II) containing 4-hydroxypyridine-2,6-dicarboxylic acid and 2-amino-4-methylpyrimidine ligands: Synthesis, X-ray crystal structure and thermalproperties
A novel binuclear complex of Cu(II) synthesized and characterized by
elemental analysis, FTIR spectroscopy, TG analysis, and single crystal X-ray
structure determination. The chemical formula and space group ...
Binuclear complex of Cu(II) containing chelidamic acid and 2-aminopyrimidine ligands: Synthesis, X-ray crystal structure,
A novel binuclear complex of Cu(II) was synthesized and characterized by using elemental analysis, FTIR spectroscopy, TG analysis,
magnetic property, and single crystal X-ray structure determination. The chemical ...
Two new complexes of VV and FeIII atoms containing 4-hydroxy-pyridine-2,6-dicarboxylic acid and 2aminopyrimidine
The reaction of the 4-hydroxy-pyridine-2,6-dicarboxylic acid (for short H3hypydc) and 2-aminopyrimidine (for short 2-apym) with
vanadiumIII and ironIII chloride in distilled water medium produces prism brown crystals ...