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Syntheses and characterization of two new coordination compounds containing an azide ligand in the presence of o‐donor co‐ligands with nickel and copper(II) metal ions and an investigation into the effects of sonochemical methods on morphology and particl
In this research, two new coordination complexes {[Ni(but-1,4-dc)0.5(N3)(H2O)]·3H2O}n (1) and {[Cu(bpc)(N3)(H2O)]·H2O}n (2) were synthesized from butane-1,4-dicarboxylate (but-1,4-dc) or benzophenone-2-carboxylate (bpc) and N3– ligands. Further...
On the importance of non covalent interactions in the structure of coordination Cu(II) and Co(II) complexes of pyrazine- and pyridine-dicarboxylic acid derivatives: Experimental and theoretical views
Three Cu and one Co complexes of three pyridine–2,6–dicarboxylic acid derivatives were synthesized by proton transfer reactions. They are formulated as {Cu[(ampym)(hypydc)(H2O)}∙H2O (1), {[Co(pyzdc)(H2O)2]•H2O}n (2), ...
The first phosphoramide–mercury(II) complex with a Cl2Hg–OP[N(C)(C)]3 segment
Mercury(II) exhibits a strong preference for linear coordination which has been attributed to relativistic effects splitting the 6p orbitals and promoting sp hybridization. If the two ligands attached to the mercury(II) ...
Synthesis And Characterization of Two New Cademium Complexes of Pyridine-2,5-Dicarboxylic Acid N-Oxide
, coordination modes, and structure types of these compounds in view of crystal engineering concepts. In this work, we report the syntheses of two new coordination complexes based on pyridine-2,5-dicarboxylic acid N-oxide (2,5-H2pydco) as a ligand with CdII metal...
Synthesis and characterization of coordination complexes of chrome and mercury metal ionscontaining pyridine-2,5-dicarboxylic acid N-oxide
coordination complexes with CrIII and one coordination complex based on the proton transfer mechanism with three heterocyclic bases such as 1,10-phenanthroline (phen), 2-aminopyrimidine (2-apym), and isonicotinamide (Ina). The ligands and complexes were...
Coordination complexes of copper and cobalt metal ions containing pyridine-2,5-dicarboxylic acid N-oxide: Synthesis and characterization
Recently, the subject of main chemical researchesis some how related to the field of noncovalent intermolecular interactions that leading to the formation of unique coordination compounds and gave rise to two new branches ...
SYNTHESIS AND CHARACTERIZATION OF TWO NEW CADMIUM COMPLEXES OF PYRIDINE-2,5-DICARBOXYLIC ACID N-OXIDE
, coordination modes, and structure types of these compounds in view of crystal engineering concepts. In this work, we report the syntheses of two new coordination complexes based on pyridine-2,5-dicarboxylic acid N-oxide (2,5-H2pydco) as a ligand with CdII metal...
Synthesis and characterization of a manganese(II) coordination complex based on highly pre-organized ligand of 1,10
The continuity of the searches for new materials with the higher performance than those used
currently are necessary in order to satisfy daily improving technology. For this purpose, the
sensible choice of ...
سنتز، شناسایی و مطالعه ی ضد تکثیری برخی از کمپلکس های متشکل از پیریدین-۶،۲-دی کربوکسیلیک اسید اُکسید شده
In this paper we report the synthesis and characterization of three new mixed-ligand cobalt and manganese complexes containing pydco = pyridine-N-oxide-2,6-dicarboxylic acid, bipy = 2,2ꞌ˗bipyridine and phen = 1,10˗phenanthroline. ...