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Synthesis of a new heterocyclic system Fluoreno[1,2-d]imidazol-10-one

Author:
محمد رحیمی زاده
,
مهدی پردل فدافن
,
مهدی بکاولی
,
شیما رضائیان
,
حسین عشقی
,
Mohammad Rahimizadeh
,
Mehdi Pordel
,
Mehdi Bakavoli
,
shima rezaeian
,
Hossein Eshghi
Year
: 2010
Abstract: Fluorenones (fluorine-9-ones) are among the oldest classes of bioactive compounds,

which are widely used as antiviral [1] and anticancer agents and act as the key synthetic

intermediates in many reactions. Also, fluorenones with a suitable functionality can be

used as a fluorescent electrophilic reagent [2]. Recently, they have mainly been

considered as an important unit in polymer chemistry. The fluorenone structural unit

provides both rigidly planarized biphenyl units within the polymer backbone and the

possibility of remote functionalization at C-9, the latter offer the prospect of improving both

polymer processibility and mediating potential interchain interactions in films [3].

Owing to our growing interest in the synthesis of bioactive heterocycles [4], we became

interested in examining the cyclization of diazotized compounds to new fluoreno [1,2-

d]imidazol-10-ones. This research has demonstrated that the cyclization of diazotized oamino-

ketones is a reliable work, which can be extended to the synthesis of other new

heterocyclic compounds.
URI: https://libsearch.um.ac.ir:443/fum/handle/fum/3378133
Keyword(s): Fluorenonesو fluorescent electrophilic reagent و heterocyclic compounds
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    Synthesis of a new heterocyclic system Fluoreno[1,2-d]imidazol-10-one

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contributor authorمحمد رحیمی زادهen
contributor authorمهدی پردل فدافنen
contributor authorمهدی بکاولیen
contributor authorشیما رضائیانen
contributor authorحسین عشقیen
contributor authorMohammad Rahimizadehfa
contributor authorMehdi Pordelfa
contributor authorMehdi Bakavolifa
contributor authorshima rezaeianfa
contributor authorHossein Eshghifa
date accessioned2020-06-06T13:59:54Z
date available2020-06-06T13:59:54Z
date copyright10/13/2010
date issued2010
identifier urihttps://libsearch.um.ac.ir:443/fum/handle/fum/3378133
description abstractFluorenones (fluorine-9-ones) are among the oldest classes of bioactive compounds,

which are widely used as antiviral [1] and anticancer agents and act as the key synthetic

intermediates in many reactions. Also, fluorenones with a suitable functionality can be

used as a fluorescent electrophilic reagent [2]. Recently, they have mainly been

considered as an important unit in polymer chemistry. The fluorenone structural unit

provides both rigidly planarized biphenyl units within the polymer backbone and the

possibility of remote functionalization at C-9, the latter offer the prospect of improving both

polymer processibility and mediating potential interchain interactions in films [3].

Owing to our growing interest in the synthesis of bioactive heterocycles [4], we became

interested in examining the cyclization of diazotized compounds to new fluoreno [1,2-

d]imidazol-10-ones. This research has demonstrated that the cyclization of diazotized oamino-

ketones is a reliable work, which can be extended to the synthesis of other new

heterocyclic compounds.
en
languageEnglish
titleSynthesis of a new heterocyclic system Fluoreno[1,2-d]imidazol-10-oneen
typeConference Paper
contenttypeExternal Fulltext
subject keywordsFluorenonesو fluorescent electrophilic reagent و heterocyclic compoundsen
identifier linkhttps://profdoc.um.ac.ir/paper-abstract-1019061.html
conference title17th Iranian Seminar Of Organic Chemistryen
conference locationبابلسرfa
identifier articleid1019061
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