| contributor author | محمدحسین ارباب زوار | en |
| contributor author | Somayeh Heydari | en |
| contributor author | غلامحسین رونقی | en |
| contributor author | Mohammad Hossein Arbab Zavar | fa |
| contributor author | Glamhossein Ronagi | fa |
| date accessioned | 2020-06-06T13:38:53Z | |
| date available | 2020-06-06T13:38:53Z | |
| date issued | 2017 | |
| identifier uri | https://libsearch.um.ac.ir:443/fum/handle/fum/3363410?show=full | |
| description abstract | Polypyrrole modified electrode prepared by electropolymerization of pyrrole in the presence of a complexing ligand, benzo-15-crown-5 (B15C5), was prepared and investigated as a La3+- selective electrode in acetonitrile. The potentiometric response of the electrode was linear within the La3+ concentration range 1 • 10_4 to 1 • 10_1 M with a Nernstian slope of 19.5 mV decade_1 in AN. The electrode was applied to study the complexation of the lanthanum (III) ion in acetonitrile with other basic solvent molecules (D) such as dimethyl sulfoxide, N,N-dimethylformamide, propylene carbonate, N,N,Diethylaniline and methanol. The successive complex formation constant (bi) and Gibbs energies of transfer (DGtr) of La3+ in AN in relation to such D were obtained. | en |
| language | English | |
| title | A PPy-B15C5 modified lanthanum (III) electrode in acetonitrile and its thermodynamic application | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | Polypyrrole | en |
| subject keywords | Electropolymerization | en |
| subject keywords | Lanthanum-selective electrode | en |
| subject keywords | Potentiometry | en |
| subject keywords | Benzo-15-crown-5 | en |
| journal title | Arabian Journal of Chemistry | fa |
| pages | 1429-1434 | |
| journal volume | 10 | |
| journal issue | 1 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1067188.html | |
| identifier articleid | 1067188 | |
