Diphenyl (isopropylamido) phosphate
Year
: 2012
Abstract: The P atom in the title compound, C15H18NO3P, is in a distorted tetrahedral P(O)(O)2N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent molecules are linked via N—H…O═P hydrogen bonds into a chain running parallel to the b axis. The methyl groups are disordered over two sets of sites in a 0.677 (14):0.323 (14) ratio. The crystal studied was a nonmerohedral twin with a refined minor component of 22.31 (4)%.
Keyword(s): single-crystal X-ray study,T 120 K,mean σ(C–C) 0,003 Å,disorder in main residue,R factor 0,027,wR factor 0,081,data-to-parameter ratio 29,9
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Diphenyl (isopropylamido) phosphate
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| contributor author | Fahimeh Sabbaghi | en |
| contributor author | مهرداد پورایوبی | en |
| contributor author | Marek Nečas | en |
| contributor author | Michal Babiak | en |
| contributor author | Mehrdad Pourayoubi | fa |
| date accessioned | 2020-06-06T13:10:30Z | |
| date available | 2020-06-06T13:10:30Z | |
| date issued | 2012 | |
| identifier uri | https://libsearch.um.ac.ir:443/fum/handle/fum/3344594 | |
| description abstract | The P atom in the title compound, C15H18NO3P, is in a distorted tetrahedral P(O)(O)2N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent molecules are linked via N—H…O═P hydrogen bonds into a chain running parallel to the b axis. The methyl groups are disordered over two sets of sites in a 0.677 (14):0.323 (14) ratio. The crystal studied was a nonmerohedral twin with a refined minor component of 22.31 (4)%. | en |
| language | English | |
| title | Diphenyl (isopropylamido) phosphate | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | single-crystal X-ray study | en |
| subject keywords | T 120 K | en |
| subject keywords | mean σ(C–C) 0 | en |
| subject keywords | 003 Å | en |
| subject keywords | disorder in main residue | en |
| subject keywords | R factor 0 | en |
| subject keywords | 027 | en |
| subject keywords | wR factor 0 | en |
| subject keywords | 081 | en |
| subject keywords | data-to-parameter ratio 29 | en |
| subject keywords | 9 | en |
| journal title | Acta Crystallographica Section E: Structure Reports Online | fa |
| pages | 3459-3459 | |
| journal volume | 68 | |
| journal issue | 12 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1031379.html | |
| identifier articleid | 1031379 |