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RISSynthesis and X-ray characterization of a new hybrid based polyoxometalates
The design and synthesis of inorganic-organic hybrid materials based on polyoxometalates (POMs) have attracted considerable attention over recent years, because of their intriguing architectures and properties as well as potential applications...
Applications of inorganic-organic hybrid architectures based on polyoxometalates in catalyzed and photocatalyzed chemical transformations
catalytic and photocatalytic reactions catalyzed by
POM-based inorganic-organic hybrid. Notably, it has been well established that depending on
the type of the reaction, the activity and selectivity of these hybrid catalyst can be drastically
On the Polymorphism of 12-Tungstoborate Heteropolyanion: Structure Determination and Its Functionalization with L-proline
A new structure related to previously reported structure of 12-tungstoborate Keggin-type polyoxometalate, K5[BW12O40], was synthesized and its characterization by single crystal X-ray diffraction shows the polymorph ...
On the Polymorphism of 12-Tungstoborate Heteropolyanion: Structure Determination and Its Functionalization with L-proline
A new structure related to previously reported structure of 12-tungstoborate Keggin-type polyoxometalate, K5[BW12O40], was synthesized and its characterization by single crystal X-ray diffraction shows the polymorph ...
Surface-grafted Europium and Erbium Complexes of the 12-Tungstosilicate Heteropolyoxometalate: A Synthetic and Structural Investigations
The hydrothermal synthesis of two new inorganic-organic hybrid materials in which PDA (PDA = 1,10-phenanthroline-2,9-dicarboxylate) is connected to a well-defined Keggin-type polyoxometalate anion (POM) and a Ln(III) cation...
An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations
Abstract
A unique ionic hybrid material [C6H12N5O]3[(PO4)W12O36] 5H2O has been synthesized from the reaction of ((1H-tetrazole-5-
yl)methyl)morpholine and a-H3[(PO4)W12O36] 21H2O. It has successfully been ...
Molecular design and crystal engineering of a novel series of inorganic-organic hybrid architectures based Keggin-type polyoxometalates
The targeted synthesis of inorganic–organic hybrid supramolecular materials through crystal engineering is a principal challenge of modern chemistry research. Polyoxometalates (POMs), as metal–oxygen cluster species, are significant inorganic...
Hydrothermal Synthesis and Crystal structure of a Three-Dimensional Networks Constructed from Keggin Anion and Lanthanide –Organic Complex
for constructing multifunctional materials [3].
In this work an inorganic–organic hybrid compound based on one-electron-reduced Keggin polyanions and 3D lanthanide-organic coordination polymer; [La(H2O)4(pdc)]4 [PMo11VIMoVO40] · H2O(1) (pdc= pyridine-2...
Purposeful molecular design of inorganic-organic hybrid architectures based Keggin-type polyoxometalates: luminescence properties and Monte Carlo simulation studies
Nowadays, the construction of inorganic-organic networks through crystal
engineering has been the subject of much interest. Polyoxometalates (POMs), which
are nanosized metal-oxide clusters and unusually ...
Developing some POMs-templated MOFs: Crystal structure, magnetic and gas adsorption properties
In the past decades, great efforts have been devoted to the rational design and
synthesis of inorganic-organic hybrid architectures and metal organic frameworks
(MOFs). A common feature of such design approaches is to employ poly...