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RISSynthesis, Crystal Structure and Hirshfeld Surface Analysis of [PdCI(PPh3)L], L: S-allyl-β-N-(benzyIidene)dithiocarbazate as NS-donor bidentate Schiff Base Ligand
Herein, as part of our longstanding efforts in the synthesis of dithiocarbazate Schiff base ligands and their complexes [1-2], the new mixed ligand palladium(Ii) with bidentate NS-dotior chelate, [PdCI(PPh3)L] L: S...
S-allyl dithiocarbazate: Cell viability and role of ligand on coordination
The coordination chemistry of dithiocarbazates as a class of Schiff bases has raised considerable interest because of their ability to form various metal complexes with different coordination numbers and geometries. These compounds have a wide range...
New diathiocarbazate Schiff base ...
Hard-soft nitrogen sulfur chelating agents in particular schiff bases derived from S-alkyl ....
Ring to open-chain transformation induced by selective metal coordination in a new dithiocarbazate ligand
By unsymmetrical derivatization of acetylacetone with S-ethyl-dithiocarbazide, a new tetradentate chelate ligand (N, N, S, S) has been prepared and studied. The compound can exist in two isomeric forms: an open tetradentate ...
Synthesis of two new Sn(IV) complexes of S-ethyl-3-(2-hydroxy-phenyl)methylene dithiocarbazate
) and [Sn(sedtc)2] (2 [sedtc: S-ethyl¬-3-(2-hydroxy¬phenyl)methylene-dithiocarbazate)], are synthesized and characterized using single crystal X-ray diffraction analysis, mass spectrometry and spectroscopic techniques such as IR, 1H- and 13C-NMR. Compounds 1...
Preparation, X-ray structure, spectral analysis, DFT calculation and thermal study on palladium(II) coordination compound with Schiff base derived from S-allyldithiocarbazate
A new palladium(II) complex of PdLCl (HL: S-allyl-3-(2-pyridyl-methylene)dithiocarbazate) has been
synthesized and characterized by elemental analysis, IR, EI-MS, UV–Vis, 1H NMR, 13C NMR, TGA and
SCXRD analysis. IR spectra reveled...
S-allyl-3-(2-pyridyl-methylene)dithiocarbazate ligand and its manganese(II), cobalt(III) and nickel(II) complexes
A new NNS tridentate ligand, S-allyl-3-(2-pyridyl-methylene)dithiocarbazate (HL) and its Mn(L)2, [Co(L)2]NO3 and Ni(L)2 complexes have been prepared and characterized with usual methods. Single crystal X-ray analysis shows that bis-chelate complexes...
Determination of Bismuth by Electrothermal Atomic Absorption Spectrometry using Single Drop Micro Extraction in Real Samples
. In this method B i3- in pH 6 during 20 min extraction time at 20°C is reacted with S-methyl-3-salicylidene dithiocarbazate (SMSDC) dissolved in 4ul of chloroform micro drop. After extraction, the micro drop was retracted and directly transferred into a graphite...
Determination of Cadmium by Electrothermal Atomic Absorption Spectrometry using Single Drop Micro Extraction in Real Samples
is described. During 20 min extraction time at 20°C is reacted with S methyl-3-salicylidene dithiocarbazate (SMSDC) dissolved in 4µl of chloroform micro drop. After extraction, the micro drop was retracted and directly transferred into a graphite tube coated...
Determination of Cadmium by Electrothermal Atomic Absorption Spectrometry
. In this method Cd 21 in pH 4 during 20 min extraction time at 20 °C is reacted with S-methyl-3-salicylidene dithiocarbazate dissolved in 4µL of chloroform micro drop. After extraction, the micro drop was retracted and directly transferred into a graphite tube...