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RISComplexation Ability of Dibenzo-24-crown-8 with Cs+ Cation in Binary Mixed Non-Aqueous Solvents
The complexation reaction of macrocyclic ligand, dibenzo-24-crown-8 (DB24C8) with Cs+ cation was studied in acetonitrile-methanol(AN-MeOH), acetonitrile-ethanol (AN-EtOH), acetonitrile-dimethylformamide(AN-DMF) and nitromethane-methanol (NM...
A Conductometric Study of Complexation Reactions Between Dibenzo-18-Crown-6 with
Macrocyclic compounds such as crown ethers are capable of forming complexes with metal cations viaelectrostatic attraction and encapsulation into the cavity[1]. Because of this ability, crown compounds have found applications ...
stability of dibenzo-18-crown-6 complexes with Ce3+ , Y3+ , UO22+ and Sr2+ cations in acetonitrile-Dimethylformamide binary solutions.
crown ethers noted fot their remarkable selectivity towards specific cations making them excellent choices for the separation of desired ions from mixture by solvent extraction and membrane transport [1,2].
A thermodynamic study of complexation of 18-crown-6 with Zn2+ ,Tl + ,Hg2+ and UO2þ 2 cations in acetonitrile-dimethylformamide binary media and study the effect of anion on the stability constant of (18C6-Na+ ) complex in methanol solutions
The equilibrium constants and thermodynamic parameters for complex formation of 18-crown-6(18C6) with Zn2+, Tl+, Hg2+ and UO2 + 2 cations have been determined by conductivity measurements in acetonitrile(AN)-dimethylformamide(DMF) ...
Thermodynamic Studies on Complexation of Cu2+, Ag+ and Tl+ Metal Cations with 4,4
logKf, DHº , DS˚,values are reported for the complexation reactions of Cu2+, Ag+ and Tl+ Metal Cations with macrocyclic ligand, 4, 4,(5)-ditert- butyldibenzyl-18-crown-6 (DTDB18C6) in Acetonitrile-Dimethylformamide Binary solutions (AN...