N,N--Dicyclopentyl-N--,N---dimethylphosphoric triamide
Author:
, , , ,Year
: 2011
Abstract: The P atom in the title molecule, C12H26N3OP, has a distorted tetrahedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclopentylamido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different intermolecular N—H…O(P) hydrogen bonds, building R22(8) rings that are further linked into chains along [001].
Keyword(s): single-crystal X-ray study,T 291 K,mean σ(C–C) 0,008 Å,R factor 0,056,wR factor 0,108,data-to-parameter ratio 17,0
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N,N--Dicyclopentyl-N--,N---dimethylphosphoric triamide
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| contributor author | Akbar Raissi Shabari | en |
| contributor author | مهرداد پورایوبی | en |
| contributor author | Farnaz Ghoreishi | en |
| contributor author | Banafsheh Vahdani | en |
| contributor author | Mehrdad Pourayoubi | fa |
| date accessioned | 2020-06-06T14:37:11Z | |
| date available | 2020-06-06T14:37:11Z | |
| date issued | 2011 | |
| identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3404296?locale-attribute=en | |
| description abstract | The P atom in the title molecule, C12H26N3OP, has a distorted tetrahedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclopentylamido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different intermolecular N—H…O(P) hydrogen bonds, building R22(8) rings that are further linked into chains along [001]. | en |
| language | English | |
| title | N,N--Dicyclopentyl-N--,N---dimethylphosphoric triamide | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | single-crystal X-ray study | en |
| subject keywords | T 291 K | en |
| subject keywords | mean σ(C–C) 0 | en |
| subject keywords | 008 Å | en |
| subject keywords | R factor 0 | en |
| subject keywords | 056 | en |
| subject keywords | wR factor 0 | en |
| subject keywords | 108 | en |
| subject keywords | data-to-parameter ratio 17 | en |
| subject keywords | 0 | en |
| journal title | Acta Crystallographica Section E: Structure Reports Online | fa |
| pages | 3401-3401 | |
| journal volume | 67 | |
| journal issue | 12 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1024474.html | |
| identifier articleid | 1024474 |