N,N--Dibenzyl-N--(2-chloroacetyl)-N,N--dimethylphosphoric triamide
Year
: 2011
Abstract: In the title molecule, C18H23ClN3O2P, the P atom is bonded in a distorted tetrahedral environment. The P=O and N—H groups are syn with respect to each other. The angles at the tertiary N atoms confirm their sp2 character. In the crystal, pairs of intermolecular P=O…H—N hydrogen bonds form centrosymmetric dimers.
Keyword(s): single-crystal X-ray study,T 120 K,mean σ(C–C) 0,003 Å,R factor 0,031,wR factor 0,083,data-to-parameter ratio 14,0
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N,N--Dibenzyl-N--(2-chloroacetyl)-N,N--dimethylphosphoric triamide
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| contributor author | مهرداد پورایوبی | en |
| contributor author | مجتبی کیخا | en |
| contributor author | Marek Nečas | en |
| contributor author | Mehrdad Pourayoubi | fa |
| contributor author | MOJTABA KEIKHA | fa |
| date accessioned | 2020-06-06T14:36:49Z | |
| date available | 2020-06-06T14:36:49Z | |
| date issued | 2011 | |
| identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3404047?locale-attribute=en | |
| description abstract | In the title molecule, C18H23ClN3O2P, the P atom is bonded in a distorted tetrahedral environment. The P=O and N—H groups are syn with respect to each other. The angles at the tertiary N atoms confirm their sp2 character. In the crystal, pairs of intermolecular P=O…H—N hydrogen bonds form centrosymmetric dimers. | en |
| language | English | |
| title | N,N--Dibenzyl-N--(2-chloroacetyl)-N,N--dimethylphosphoric triamide | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | single-crystal X-ray study | en |
| subject keywords | T 120 K | en |
| subject keywords | mean σ(C–C) 0 | en |
| subject keywords | 003 Å | en |
| subject keywords | R factor 0 | en |
| subject keywords | 031 | en |
| subject keywords | wR factor 0 | en |
| subject keywords | 083 | en |
| subject keywords | data-to-parameter ratio 14 | en |
| subject keywords | 0 | en |
| journal title | Acta Crystallographica Section E: Structure Reports Online | fa |
| pages | 2439-2439 | |
| journal volume | 67 | |
| journal issue | 9 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1023989.html | |
| identifier articleid | 1023989 |