Bis(2,6-diaminopyridinium) hydrogen phthalate nitrate monohydrate
Year
: 2010
Abstract: The title hydrated salt, 2C5H8N3
+.C8H5O4-. NO3-.H2O, was
obtained fortuitously from the reaction between 2,6-diaminopyridine,
phthalic acid and Co(NO3)2.6H2O at 343 K. The
asymmetric unit consists of two crystallographically independent
2,6-diaminopyridinium cations, a hydrogen phthalate
anion, a nitrate ion and a water molecule of crystallization
which in the crystal structure are linked by intermolecular O—
H...O and N—H...O hydrogen bonds into a three-dimensional
network. In the hydrogen phthalate anion, there is a
very strong intramolecular O—H...O hydrogen bond.
+.C8H5O4-. NO3-.H2O, was
obtained fortuitously from the reaction between 2,6-diaminopyridine,
phthalic acid and Co(NO3)2.6H2O at 343 K. The
asymmetric unit consists of two crystallographically independent
2,6-diaminopyridinium cations, a hydrogen phthalate
anion, a nitrate ion and a water molecule of crystallization
which in the crystal structure are linked by intermolecular O—
H...O and N—H...O hydrogen bonds into a three-dimensional
network. In the hydrogen phthalate anion, there is a
very strong intramolecular O—H...O hydrogen bond.
Keyword(s): single-crystal X-ray study,T 120 K,mean (C–C) 0,004 A°,
R factor 0,046,wR factor 0,093,data-to-parameter ratio 9,2
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Bis(2,6-diaminopyridinium) hydrogen phthalate nitrate monohydrate
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| contributor author | A. Raissi Shabari | en |
| contributor author | M. Safaeimovahed | en |
| contributor author | مهرداد پورایوبی | en |
| contributor author | Mehrdad Pourayoubi | fa |
| date accessioned | 2020-06-06T14:17:11Z | |
| date available | 2020-06-06T14:17:11Z | |
| date issued | 2010 | |
| identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3390156?locale-attribute=en | |
| description abstract | The title hydrated salt, 2C5H8N3 +.C8H5O4-. NO3-.H2O, was obtained fortuitously from the reaction between 2,6-diaminopyridine, phthalic acid and Co(NO3)2.6H2O at 343 K. The asymmetric unit consists of two crystallographically independent 2,6-diaminopyridinium cations, a hydrogen phthalate anion, a nitrate ion and a water molecule of crystallization which in the crystal structure are linked by intermolecular O— H...O and N—H...O hydrogen bonds into a three-dimensional network. In the hydrogen phthalate anion, there is a very strong intramolecular O—H...O hydrogen bond. | en |
| language | English | |
| title | Bis(2,6-diaminopyridinium) hydrogen phthalate nitrate monohydrate | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | single-crystal X-ray study | en |
| subject keywords | T 120 K | en |
| subject keywords | mean (C–C) 0 | en |
| subject keywords | 004 A° | en |
| subject keywords | R factor 0 | en |
| subject keywords | 046 | en |
| subject keywords | wR factor 0 | en |
| subject keywords | 093 | en |
| subject keywords | data-to-parameter ratio 9 | en |
| subject keywords | 2 | en |
| journal title | Acta Crystallographica Section E: Structure Reports Online | fa |
| pages | 551-551 | |
| journal volume | 66 | |
| journal issue | 3 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1013901.html | |
| identifier articleid | 1013901 |