Synthesis, characterization and crystal structure of Indium(ш) binuclear complex containing pyridine-2,3 dicarboxylic acid
Author:
, , , , ,Year
: 2011
Abstract: The novel centrosymmetric complex, [In2(pydc)2(pydcH)2(H2O)2] • 2H2O (1), (pydcH2 = 2,3-pyridinedicarboxylic acid) was
synthesized and thoroughly characterized using elemental analysis, IR, 1H NMR spectroscopy and single crystal X-ray diffraction. All of
obtained data via routine methods are in agreement with single crystal X-ray diffraction information. Compound 1 crystallized in the
triclinic system with space group Pī with two molecules per unit cell. Each In(III) is six-coordinated with InN2O4 bound set as distorted
octahedral geometry. PydcH2 with capability hydrogen donating and versatile coordination mode appears in this complex as both mono
depronotaed, bidenated ligand and doubly protonated-tridentate one. Each tridentate ligands is coordinated to In(III) through two O
atoms and one N atom and play as bridged role between two In(III) ions. The distance between two In(III) is about 6.527 Å and size of
resultant hole within binuclear complex is around 3.195×5.567Å2. In the title compound, different types of hydrogen bonds and
electrostatic interaction play important roles in stabilizing the corresponding lattice and assemble to 3-D supramoleculer network.
synthesized and thoroughly characterized using elemental analysis, IR, 1H NMR spectroscopy and single crystal X-ray diffraction. All of
obtained data via routine methods are in agreement with single crystal X-ray diffraction information. Compound 1 crystallized in the
triclinic system with space group Pī with two molecules per unit cell. Each In(III) is six-coordinated with InN2O4 bound set as distorted
octahedral geometry. PydcH2 with capability hydrogen donating and versatile coordination mode appears in this complex as both mono
depronotaed, bidenated ligand and doubly protonated-tridentate one. Each tridentate ligands is coordinated to In(III) through two O
atoms and one N atom and play as bridged role between two In(III) ions. The distance between two In(III) is about 6.527 Å and size of
resultant hole within binuclear complex is around 3.195×5.567Å2. In the title compound, different types of hydrogen bonds and
electrostatic interaction play important roles in stabilizing the corresponding lattice and assemble to 3-D supramoleculer network.
Keyword(s): [In2(pydc)2(pydcH)2(H2O)2] • 2H2O
Collections
:
-
Statistics
Synthesis, characterization and crystal structure of Indium(ш) binuclear complex containing pyridine-2,3 dicarboxylic acid
Show full item record
| contributor author | حسین اشتیاق حسینی | en |
| contributor author | مسعود میرزائی شهرابی | en |
| contributor author | بی بی اعظم موسوی نژاد | en |
| contributor author | Hossein Eshtiagh Hosseini | fa |
| contributor author | Masoud Mirzaei Shahrabi | fa |
| contributor author | bibi azam moosavi nejad | fa |
| date accessioned | 2020-06-06T14:02:43Z | |
| date available | 2020-06-06T14:02:43Z | |
| date copyright | 9/4/2011 | |
| date issued | 2011 | |
| identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3380110?locale-attribute=en | |
| description abstract | The novel centrosymmetric complex, [In2(pydc)2(pydcH)2(H2O)2] • 2H2O (1), (pydcH2 = 2,3-pyridinedicarboxylic acid) was synthesized and thoroughly characterized using elemental analysis, IR, 1H NMR spectroscopy and single crystal X-ray diffraction. All of obtained data via routine methods are in agreement with single crystal X-ray diffraction information. Compound 1 crystallized in the triclinic system with space group Pī with two molecules per unit cell. Each In(III) is six-coordinated with InN2O4 bound set as distorted octahedral geometry. PydcH2 with capability hydrogen donating and versatile coordination mode appears in this complex as both mono depronotaed, bidenated ligand and doubly protonated-tridentate one. Each tridentate ligands is coordinated to In(III) through two O atoms and one N atom and play as bridged role between two In(III) ions. The distance between two In(III) is about 6.527 Å and size of resultant hole within binuclear complex is around 3.195×5.567Å2. In the title compound, different types of hydrogen bonds and electrostatic interaction play important roles in stabilizing the corresponding lattice and assemble to 3-D supramoleculer network. | en |
| language | English | |
| title | Synthesis, characterization and crystal structure of Indium(ш) binuclear complex containing pyridine-2,3 dicarboxylic acid | en |
| type | Conference Paper | |
| contenttype | External Fulltext | |
| subject keywords | [In2(pydc)2(pydcH)2(H2O)2] • 2H2O | en |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1023246.html | |
| conference title | 15th Iranian chemistry congress | en |
| conference location | همدان | fa |
| identifier articleid | 1023246 |