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Optical study of Xanthene type dyes in nano-confined liquid

Author:
سید مهدی شواکندی
,
خلیل علی زاده
,
سهیل شریفی
,
Othmar Marti
,
Masoud Amirkhani
,
khalil alizadeh
,
Soheil SHarifi
Year
: 2017
Abstract: The optical activity of dye molecules in different environments is of great interest for

many applications such as laser system or biological imaging. We investigate the

fluorescence and absorption spectrum of nano-confined Xanthene dyes (Rhodamine

B and Fluorescein sodium salt) in a two-phase liquid. Each shows very distinct optical

behavior in the water phase of a reverse microemulsion. Their optical properties such

as absorption and fluorescence for different dye and nanodroplets concentration are

investigated. We show that for the same concentration of dye in the microemulsion the

peak of fluorescence intensity is varied by altering the concentration of nanodroplets.

However, the trend of the change is widely different depending on the hydrophobicity

of dyes. Quantum–mechanical second order perturbation theory is used to calculate

the ratio of dipole moments in the ground and exacted states, which accounts for

Stokes shift of fluorescence peak. Photon correlation spectroscopy is employed to

check the trace of dye in the oil phase of the microemulsion
URI: http://libsearch.um.ac.ir:80/fum/handle/fum/3359324
Keyword(s): Fluorescnce,Absorption,Spectroscopy,Dyes,Microemulsion,Encapsulation
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    Optical study of Xanthene type dyes in nano-confined liquid

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contributor authorسید مهدی شواکندیen
contributor authorخلیل علی زادهen
contributor authorسهیل شریفیen
contributor authorOthmar Martien
contributor authorMasoud Amirkhanien
contributor authorkhalil alizadehfa
contributor authorSoheil SHarififa
date accessioned2020-06-06T13:32:50Z
date available2020-06-06T13:32:50Z
date issued2017
identifier urihttp://libsearch.um.ac.ir:80/fum/handle/fum/3359324?locale-attribute=en
description abstractThe optical activity of dye molecules in different environments is of great interest for

many applications such as laser system or biological imaging. We investigate the

fluorescence and absorption spectrum of nano-confined Xanthene dyes (Rhodamine

B and Fluorescein sodium salt) in a two-phase liquid. Each shows very distinct optical

behavior in the water phase of a reverse microemulsion. Their optical properties such

as absorption and fluorescence for different dye and nanodroplets concentration are

investigated. We show that for the same concentration of dye in the microemulsion the

peak of fluorescence intensity is varied by altering the concentration of nanodroplets.

However, the trend of the change is widely different depending on the hydrophobicity

of dyes. Quantum–mechanical second order perturbation theory is used to calculate

the ratio of dipole moments in the ground and exacted states, which accounts for

Stokes shift of fluorescence peak. Photon correlation spectroscopy is employed to

check the trace of dye in the oil phase of the microemulsion
en
languageEnglish
titleOptical study of Xanthene type dyes in nano-confined liquiden
typeJournal Paper
contenttypeExternal Fulltext
subject keywordsFluorescnceen
subject keywordsAbsorptionen
subject keywordsSpectroscopyen
subject keywordsDyesen
subject keywordsMicroemulsionen
subject keywordsEncapsulationen
journal titleJournal of Physics D: Applied Physicsfa
pages155301-155310
journal volume50
journal issue15
identifier linkhttps://profdoc.um.ac.ir/paper-abstract-1060362.html
identifier articleid1060362
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