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Polyphosphoric acid supported on silica-coated NiFe2O4 nanoparticles: An efficient and magnetically-recoverable catalyst for N-formylation of amines

Author:
امیر خجسته نژاد گل مکانی
,
محمد رحیمی زاده
,
Farid Moeinpour
,
حسین عشقی
,
مهدی بکاولی
,
Amir khojastehnezhad golmakani
,
Mohammad Rahimizadeh
,
Hossein Eshghi
,
Mehdi Bakavoli
Year
: 2014
Abstract: A rapid, green and simple method for the N-formylation of various aromatic amines with

formic acid using polyphosphoric acid supported on silica-coated NiFe2O4 magnetic

nanoparticles (NiFe2O4@SiO2–PPA) under solvent-free conditions at room temperature

has been developed. The magnetic catalyst can be easily removed by a simple magnet and

reused at least three times without any loss of its high catalytic activity. In addition to its

facility, this protocol enhances product purity and promises economic and also environmental profits.
URI: http://libsearch.um.ac.ir:80/fum/handle/fum/3347940
Keyword(s): Amines,N-formylation,Magnetic recovery,Polyphosphoric acid,Silica-coated NiFe2O4
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    Polyphosphoric acid supported on silica-coated NiFe2O4 nanoparticles: An efficient and magnetically-recoverable catalyst for N-formylation of amines

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contributor authorامیر خجسته نژاد گل مکانیen
contributor authorمحمد رحیمی زادهen
contributor authorFarid Moeinpouren
contributor authorحسین عشقیen
contributor authorمهدی بکاولیen
contributor authorAmir khojastehnezhad golmakanifa
contributor authorMohammad Rahimizadehfa
contributor authorHossein Eshghifa
contributor authorMehdi Bakavolifa
date accessioned2020-06-06T13:15:33Z
date available2020-06-06T13:15:33Z
date issued2014
identifier urihttp://libsearch.um.ac.ir:80/fum/handle/fum/3347940?locale-attribute=en
description abstractA rapid, green and simple method for the N-formylation of various aromatic amines with

formic acid using polyphosphoric acid supported on silica-coated NiFe2O4 magnetic

nanoparticles (NiFe2O4@SiO2–PPA) under solvent-free conditions at room temperature

has been developed. The magnetic catalyst can be easily removed by a simple magnet and

reused at least three times without any loss of its high catalytic activity. In addition to its

facility, this protocol enhances product purity and promises economic and also environmental profits.
en
languageEnglish
titlePolyphosphoric acid supported on silica-coated NiFe2O4 nanoparticles: An efficient and magnetically-recoverable catalyst for N-formylation of aminesen
typeJournal Paper
contenttypeExternal Fulltext
subject keywordsAminesen
subject keywordsN-formylationen
subject keywordsMagnetic recoveryen
subject keywordsPolyphosphoric aciden
subject keywordsSilica-coated NiFe2O4en
journal titleComptes Rendus Chimiefa
pages459-464
journal volume17
journal issue5
identifier linkhttps://profdoc.um.ac.ir/paper-abstract-1037910.html
identifier articleid1037910
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