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RISAnalysis of S—P—N and N—P—N angles in phosphorothioic triamides
The S—P—N and N—P—N bond angles have been analyzed in 30 phosphorothioic triamides structures (having a P(S)[N]3 skeleton) deposited in the Cambridge Structural Database (CSD, version 5.34, May 2013 update) and a new ...
Two new thiophosphoramide structures: N,N',N"-tricyclohexylphosphorothioic triamide and O,O'-diethyl (2-phenylhydrazin-1-yl)thiophosphonate
The compound N,N',N"-tricyclohexylphosphorothioic triamide, C18H36N3PS or P(S)[NHC6H11]3, (I), crystallizes in the space group Pnma with the molecule lying across a mirror plane; one N atom lies on the mirror plane, whereas ...
New 2-pyridinealdehyde N4-hydroxyethyl thiosemicarbazone and their Cd(II) and Cu(II) complexes: synthesis, spectral,
N4-hydroxyethyl-pyridinealdehyde thiosemicarbazone (HL, 1) as a tridentate Schiff base has been synthesized by 1:1 reaction of S-methyl-3-((pyridyl)methyl) dithiocarbazate and 2-aminoethanol. Complexes [Cd(HL)2](NO3)2 (2), ...
Differences in the geometries of compounds with [O]nP(O)[N]3–n, [O]nP(S)[N]3–n and [C]mP(O)[N]3–m (n = 0, 1, 2, 3; m = 1, 2, 3) segments: A Cambridge Structural Database analysis completed with fourteen new structures
Recently, we reported on the analysis of hydrogen bond pattern in different families of phosphorous(V) compounds, considering the structure determination of some derivatives and the study of analogous structures deposited ...