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RISCrystal structure and Hirshfeld surface analysis of [S-(–)(C6H5)CH(CH3)NP(S)NH(S)-(–)CH(CH3)(C6H5)]2,H2O
The cyclic compound [S-(–)-(C6H5)CH(CH3)NP(S)NH(S)-(–)-CH(CH3)(C6H5)]2,H2O, or C32H38N4P2S2,H2O is a member of a class of molecules that may be used for extraction of metals. The literature shows many studies of the bidentate ...
SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (4-Cl-C6H4O)(OC4H8N)2PO AMIDOPHOSPHOESTER
A new amidophosphoester, (4-Cl-C6H4O)(OC4H8N)2PO, was synthesized and characterized by spectroscopic methods (IR, 31P-, 13C-, 1H-NMR) and single-crystal X-ray diffraction. The crystal belongs to the space group P21/c, and ...
Hirshfeld surface analysis of new phosphoramidates
Hirshfeld surfaces and two-dimensional fingerprint plots are used to visualize and analyze intermolecular interactions in six new phosphoramidate structures, [2,6-F2—C6H3C(O)NH]P(O)[X]2 {X = N(C2H5)2 (1), [X]2 = NHCH2C(CH3)2CH2NH ...
A new Z′ = (2 +0.5 +0.5) amidophosphoester structure: Hirshfeld surface analysis of symmetry- independent molecules
Tetraethyl 1,3-phenylenebis(phosphoramidate) was synthesized and characterized by 1H, 13C, 31P NMR, IR and mass spectroscopies. The asymmetric unit is composed of two half-molecules, each residing on a twofold axis, and ...
The first Fe(II) complex bearing end-to-end dicyanamide as a double bridging ligand: Crystallography study and Hirshfeld surface analysis; completed with a CSD survey
Two new polymeric, one and two-dimensional compounds [Fe(dmbpy)(μ1,5-dca)2] (1) and
[Fe(4,4'-bpy)(μ1,5-dca)2].0.24(4,4'-bpy).0.5(EtOH) (2), in which dmbpy=5,5'-dimethylbipyridine,
dca = dicyanamide and 4,4'-bpy ...
Synthesis, Spectroscopic Study, X-Ray Crystallography Investigation and Hirshfeld Surface Analysis of Three New Phosphorous-Nitrogen Compounds
New phosphorous-nitrogen compounds 2,3-F2—C6H3C(O)NHP(O)[N(CH3)CH2C6H5]2 (I), C6H5OP(O)[NHCH(CH3)2]2 (II) and (CH3O)2P(S)[NHC6H4NH]P(S)(OCH3)2 (III) were synthesized and characterized by 19F NMR for (I) and 1H, 13C, 31P ...
Hirshfeld surface analysis of two new amidophosphinates
Hirshfeld surfaces and 2D fingerprint plots are used to analysis of intermolecular interactions in two new amidophosphinates: (2–Cl–C6H4O)P(O)[X]2 {X = NHC5H10 (I), [X]2= NHCH2CH2CH2NH (II)}. The N—H…O=P hydrogen bonds are ...
Hirshfeld surface analysis of two new phosphorothioic triamide structures
Hirshfeld surfaces and two-dimensional fingerprint plots are used to analyse the intermolecular interactions in two new phosphorothioic triamide structures, namely N,N',N"-tris(3,4-dimethylphenyl)phosphorothioic triamide ...
Crystal Structure (X-ray) and Solid State Computational (DFT/Hirshfeld Surface) Study for Probing the New Efficient and Recyclable Oxidant of 1,2-Ethandiylbis(triphenylphosphonium) Peroxodisulfate Dihydrate
A new efficient and recyclable oxidant for oxidation of benzylic alcohols, 1,2-Ethandiylbis(triphenylphosphonium) Peroxodisulfate Dihydrate (I) has been synthesized and characterized by IR, NMR spectroscopy and single ...
Mixed Ligand Palladium(II) Complex with NS-Bidentate S-Allyldithiocarbazate Schiff Base: Synthesis, Spectral Characterization, Crystal Structure and Decoding Intermolecular Interactions with Hirshfeld Surface Analysis
Hirshfeld surface analysis showed the presence of π…π, N…π, C—H…π, Cl…H and weak C—H…S interactions as most important intermolecular interactions in the crystal lattice, which are responsible to extension of the supramolecular network of the compound...