A Novel Hybrid Material Based on Two Symmetrically Independent Keggin
Year
: 2008
Abstract: Novel polyoxometalate-based organic-inorganic hybrid [NH3-CH(CH3)COOH][H3O]8[PMo12O40]3.4NH3CH(CH3)COO was
synthesized and characterized by 31P, 1H, 13C NMR and IR spectroscopies, elemental analysis and single crystal X-ray
determination. Two of the PMo12O40
3- anions in the title hybrid are symmetrically equivalent. They are crystallographically
independent from the third PMo12O40
3- polyoxoanion, in the case of various interactions with neighboring components in the
crystal network (i.e. +NH3-CH(CH3)-COOH and H3O+ cations, +NH3CH(CH3)COO- zwitterions and polyoxoanions). The
compound crystallizes in an orthorhombic C222 space group with a = 16.0392(16) Å, b = 34.480(4) Å, c = 12.8968(13) Å and Z
= 2.
synthesized and characterized by 31P, 1H, 13C NMR and IR spectroscopies, elemental analysis and single crystal X-ray
determination. Two of the PMo12O40
3- anions in the title hybrid are symmetrically equivalent. They are crystallographically
independent from the third PMo12O40
3- polyoxoanion, in the case of various interactions with neighboring components in the
crystal network (i.e. +NH3-CH(CH3)-COOH and H3O+ cations, +NH3CH(CH3)COO- zwitterions and polyoxoanions). The
compound crystallizes in an orthorhombic C222 space group with a = 16.0392(16) Å, b = 34.480(4) Å, c = 12.8968(13) Å and Z
= 2.
Keyword(s): Hybrid material,Symmetrically independent Keggin polyoxoanions,Crystal structure,Alanine
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A Novel Hybrid Material Based on Two Symmetrically Independent Keggin
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| contributor author | مهرداد پورایوبی | en |
| contributor author | A.R. Mahjoub | en |
| contributor author | Mehrdad Pourayoubi | fa |
| date accessioned | 2020-06-06T14:02:56Z | |
| date available | 2020-06-06T14:02:56Z | |
| date issued | 2008 | |
| identifier uri | http://libsearch.um.ac.ir:80/fum/handle/fum/3380264 | |
| description abstract | Novel polyoxometalate-based organic-inorganic hybrid [NH3-CH(CH3)COOH][H3O]8[PMo12O40]3.4NH3CH(CH3)COO was synthesized and characterized by 31P, 1H, 13C NMR and IR spectroscopies, elemental analysis and single crystal X-ray determination. Two of the PMo12O40 3- anions in the title hybrid are symmetrically equivalent. They are crystallographically independent from the third PMo12O40 3- polyoxoanion, in the case of various interactions with neighboring components in the crystal network (i.e. +NH3-CH(CH3)-COOH and H3O+ cations, +NH3CH(CH3)COO- zwitterions and polyoxoanions). The compound crystallizes in an orthorhombic C222 space group with a = 16.0392(16) Å, b = 34.480(4) Å, c = 12.8968(13) Å and Z = 2. | en |
| language | English | |
| title | A Novel Hybrid Material Based on Two Symmetrically Independent Keggin | en |
| type | Journal Paper | |
| contenttype | External Fulltext | |
| subject keywords | Hybrid material | en |
| subject keywords | Symmetrically independent Keggin polyoxoanions | en |
| subject keywords | Crystal structure | en |
| subject keywords | Alanine | en |
| journal title | Journal of the Iranian Chemical Society | fa |
| pages | 430-435 | |
| journal volume | 5 | |
| journal issue | 3 | |
| identifier link | https://profdoc.um.ac.ir/paper-abstract-1011546.html | |
| identifier articleid | 1011546 |