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RISApplications of inorganic-organic hybrid architectures based on polyoxometalates in catalyzed and photocatalyzed chemical transformations
The scope of this article is to reveal the fruitful combination of POM species with metal
coordination complexes, leading to the construction of several efficient multifunctional catalysts.
In this review, we try ...
Synthesis of Pyrazolo‐[4́,3́:5,6]pyrido[2,3‐d]pyrimidine‐diones Catalyzed by a Nano‐sized Surface‐Grafted Neodymium Complex of the Tungstosilicate via Multicomponent Reaction
An inorganic–organic hybrid based on lanthanide clusters and Keggin type polyoxometalates (POMs) (Na[Nd (pydc‐OH)(H2O)4]3}[SiW12O40]) was used the first time as trinuclear catalyst for one pot synthesis of pyrazolo[4́́,3 ...
Investigation of the uncommon basic properties of [Ln(W5O18)2]9– (Ln = La, Ce, Nd, Gd, Tb) by changing central lanthanoids in the syntheses of pyrazolopyranopyrimidines
Five Lindqvist-type lanthanopolyoxometalates ([Ln(W5O18)2]
9–, Ln = La, Ce, Nd, Gd, Tb) complexes were prepared and fully characterized. Their basic catalytic activity was manipulated in the successful and high yielding ...
Chemoselective synthesis of drug-like pyrrolo[2,3,4-kl]acridin-1-one using Polyoxometalate@Lanthanoid catalyst
The incorporation of polyoxometalates (POMs) or metal oxides into the metal-organic
frameworks (MOFs) opens new research avenues for the synthesis of heterogeneous catalysts. In this project, a catalytic system based ...
Synthesis, characterization and crystal structure analysis of a novel oxo-centered mixed-metal complex containing unsaturated bridging carboxylates
A novel oxo-centered trinuclear mixed-metal carboxylate complex with unsaturated bridging ligands [Fe2Cr(μ3-O)(C3H3O2)6(H2O)3]•NO3
•4H2O has been synthesized and characterized by means of Elemental analyses, Infrared ...
Hydrothermal Synthesis and Crystal structure of a Three-Dimensional Networks Constructed from Keggin Anion and Lanthanide –Organic Complex
The construction of metal-organic frameworks (MOFs) has been an area of rapid growth in recent years, because of their structure diversity and potential applications as functional materials [1]. Polyoxometalates (POMs), ...
Synthesis, characterization, and IR investigation of novel oxo-centerted, ....
Oxo-centered trinuclear carboxylates are a well-established class...
Synthesiz and characterization analysis of new oxo-bridged , trimer of mixed-metal complexes with acrylic acid
Oxo-centered trinuclear mixed-metal complexes ...
Purposeful molecular design of inorganic-organic hybrid architectures based Keggin-type polyoxometalates: luminescence properties and Monte Carlo simulation studies
Nowadays, the construction of inorganic-organic networks through crystal
engineering has been the subject of much interest. Polyoxometalates (POMs), which
are nanosized metal-oxide clusters and unusually ...