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RISConductance study of the thermodynamics of Co2+,Ni2+,Cu2+ cryptates in mixed acetonitrile-ethylacetate binary solvent solutions at different temperatures
complexes between C222 and Co2+, Ni2+and Cu2+ cations at 250C in the binary solution of AN-EtOAc(mol % AN 20) is :(C222. Co)2+> (C222. Ni) 2+>
(C222. Cu) 2+,but in case of another AN-EtOAc binary solvent solution (mol % AN 25) it was found to be : (C222...
Electrical Conductance study of interactions of Cu2+ , Co2+ and Ni2+ metal cations with kryptofix-21 in acetonitrile - ethanol binary solvent solution
were determined using a computer program, GENPLOT. The stability order of complexes
between kryptofix -21 and Co2+, Ni2+, Cu2+ cations at 250C in the binary solvent solution of AN- EtOH (mol % AN 0) is : ( kryptofix-21. Ni ) 2+ > (kryptofix...
Conductometric Study of Complex Formation between Benzylbisthiosemicarbazone and Metal Cations in Acetonitrile, Dimethylformamide, and Their Binary Mixtures
–dimethylformamide binary solvents of varied composition. The equilibrium constant and standard thermodynamic parameters (ΔcH0 and ΔcS0) of the complexes formation have been determined and found to be dependent on the binary solvent composition, the metal ion nature...
Complex Formation between 2,9-Dihydroxy-1,10-diphenoxy-4,7-dithiadecane and La3+, UO2 2+, Ce3+, and Y3+Cations in Acetonitrile–Ethyl Acetate Binary Media as Studied by Conductometry
at the same temperature is as follows: UO2
2+ > La3+ ≈Y3+ > Ce3+. Standard thermodynamic parameters of the complexation reaction (ΔcH0 and ΔcS0) have been determined and found to be affected by the metal ion nature and the binary solvent
composition....