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Crystal structure of dichlorobis(4-amino-1,2,4-triazole)dimethyltin(IV), SnCl2(CH3)2(C2H4N4)2
C6H14Cl2N8Sn, monoclinic, P121/c1 (no. 14), a = 8.689(2) Å,
b = 7.524(3) Å, c = 11.359(3) Å, ' = 109.86(1)°, V = 698.5 Å3,
Z = 2, Rgt(F) = 0.023, wRref(F2) = 0.057, T = 293 K.
New phosphorus (V) – nitrogen compounds: synthesis, spectroscopic characterization and X-ray crystallography studies
The phosphoramides [CClF2C(O)NH]P(O)[NC4H8]2 (1), [CF3C(O)NH]P(O)[NHC3H7]2 (2), [(2,3-F2)C6H3C(O)NH]P(O)[NHC6H11]2 (3) and [(2,3-F2)C6H3C(O)NH]P(O)[NHC3H5]2 (4) and thiophosphoramide [(4-Cl)C6H4NH]P(S)[OCH3]2 (5) were ...
Analysis of N—H…O hydrogen bonds in new C(O)—NH—P(O)-based phosphoric triamides and analogous structures deposited in the Cambridge Structural Database
Five new compounds belonging to the phosphoric triamide family have been synthesized: two of them with the formula XC(O)NHP(O)Y [X = CF3 (1) and CClF2 (2), Y = NHCH2C(CH3)2CH2NH] involving a 1,3-diazaphosphorinane ring ...
Hirshfeld surface analysis of new phosphoramidates
Hirshfeld surfaces and two-dimensional fingerprint plots are used to visualize and analyze intermolecular interactions in six new phosphoramidate structures, [2,6-F2—C6H3C(O)NH]P(O)[X]2 {X = N(C2H5)2 (1), [X]2 = NHCH2C(CH3)2CH2NH ...
Differences in the geometries of compounds with [O]nP(O)[N]3–n, [O]nP(S)[N]3–n and [C]mP(O)[N]3–m (n = 0, 1, 2, 3; m = 1, 2, 3) segments: A Cambridge Structural Database analysis completed with fourteen new structures
Recently, we reported on the analysis of hydrogen bond pattern in different families of phosphorous(V) compounds, considering the structure determination of some derivatives and the study of analogous structures deposited ...