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The Structural Study of [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4-CH3]2
A new phosphoric triamide with the formula [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4-CH3]2 has been investigated by spectroscopic methods and X-ray crystallography. This compound crystallizes in the monoclinic system, with P21/c space ...
The first phosphorothioic triamide–mercury (II) complex with a P(S)[N]3–based ligand: Synthesis and crystal structure of PS(NC5H10)3 and [Hg{P(S)(NC5H10)3}Cl2]2
The synthesis, spectral study and X-ray crystal structure of PS(NC5H10)3 phosphorothioic triamide (compound 1) and its dinuclear mercury(II) complex, [Hg{P(S)(NC5H10)3}Cl2]2 (compound 2), were investigated. The structure ...
The First C(O) NHP (O)- based Phosphoric Triamide Structure With an N–H ••• π Hydrogen Bonding: A Combination of X-ray Crystallography And Theoretical Study to Evaluate The Strength of Hydrogen Bonds
The hydrogen bond pattern of N-(4-methoxybenzoyl)-N',N"-bis(4-methylbenzyl)-phosphoric triamide, C24H28N3O3P, (I), was investigated. In the crystal structure, the molecules are aggregated through NCP–H•••O═P and NP–H•••O═C ...
The first X-ray crystal structure of a mercury-II- complex with an SP-N-3-based ligand: Synthesis and crystal structure of SP-NC5H10-3 and [Hg{SP-NC5H10-3}Cl2]2
The synthesis, spectral characteristics -IR and NMR-, elemental analysis and X-ray crystal structure of phosphorothioic triamide SP-NC5H10-3 -1- and its dinuclear mercury-II- complex [Hg2-μ-Cl-2-Cl-2{SP-NC5H10-3}2] -2- ...
Synthesis, Spectroscopic Study, X-Ray Crystallography Investigation and Hirshfeld Surface Analysis of Three New Phosphorous-Nitrogen Compounds
New phosphorous-nitrogen compounds 2,3-F2—C6H3C(O)NHP(O)[N(CH3)CH2C6H5]2 (I), C6H5OP(O)[NHCH(CH3)2]2 (II) and (CH3O)2P(S)[NHC6H4NH]P(S)(OCH3)2 (III) were synthesized and characterized by 19F NMR for (I) and 1H, 13C, 31P ...
New phosphorus (V) – nitrogen compounds: synthesis, spectroscopic characterization and X-ray crystallography studies
The phosphoramides [CClF2C(O)NH]P(O)[NC4H8]2 (1), [CF3C(O)NH]P(O)[NHC3H7]2 (2), [(2,3-F2)C6H3C(O)NH]P(O)[NHC6H11]2 (3) and [(2,3-F2)C6H3C(O)NH]P(O)[NHC3H5]2 (4) and thiophosphoramide [(4-Cl)C6H4NH]P(S)[OCH3]2 (5) were ...
Analysis of hydrogen bond directionality in phosphoric triamides
Six new crystal structures, [4-Cl-C6H4C(O)NH]P(O)[NR1R2]2 (NR1R2 = N(CH2C6H5)2 (1), NHCH2C6H5 (2), NHC6H4(4-CH3) (3)) and [RC(O)NH]P(O)[N(CH3)(CH2C6H5)]2 (R = 3-F-C6H4 (4), (3,5-F2)C6H3 (5)) and [(3,5-F2)C6H3C(O)NH]P(O)[NH]2C5H10 ...