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RISDeveloping a magnetic metal organic framework of copper bearing a mixed azido/butane-1,4-dicarboxylate bridge: Magnetic and gas adsorption properties
A magnetic metal organic framework {[Cu(but-1,4-dc)0.5(N3)(H2O)]·H2O}n (MFUM-1(Cu)) (but-1,4-dc = butane-1,4-dicarboxylate) was synthesized and characterized structurally and magnetically. In MFUM-1(Cu), each CuII ion has ...
Seven and eight-coordinate Fe(III) complexes containing pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylic acid: Solvent effects, supramolecular interactions and DFT calculations
This study reports the synthesis of two novel transition metal complexes using tetradentate 1,10-phenanthroline-2,9-dicarboxylic acid (H2PDA) as a main ligand and 1,10-phenanthroline (phen) as an auxiliary N-donor ligand.The ...
New Nano-Structured Hybrid Materials-based Polyoxometalate for CH4/H2 Separation: A Computational Study
Global climate change is one of the most serious and formidable challenges in the world. After carbon dioxide that is well-known as the most important greenhouse gas, methane has been ranked the second. On the other hand, ...
Robust PSD determination of micro and meso-pore adsorbents via novel modified U curve method
Proper estimation of pore size distribution (PSD) for various solid adsorbents is essential for efficient characterization of such materials. PSD determination is inherently an ill-posed problem which can be solved by ...