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RISSynthesis and Crystal Structure of a New Hydrated Phosphinate Salt, [(C6H5CH2)2NH2][(C6H5)2P(O)(O)].H2O
The asymmetric unit of the title hydrated salt contains one [(C6H5CH2)2NH2]+ cation, one [(C6H5)2P(O)(O)]– anion and one solvent water molecule. In the anion, the P atom is in a distorted tetrahedral [C]2P[O][O] environment ...
Two new phosphinic amides: Synthesis, crystal structure, and theoretical study of hydrogen bonding
Two novel phosphinic amides, (C6H5)2P(O)(NH–cyclo–C7H13) (I) and (C6H5)2P(O)(NH–cyclo–C6H11) (II) were synthesized and characterized by spectroscopicmethods and X-ray crystallography. Both compounds crystallize in the orthorhombic chiral space group...
Synthesis and characterization of phosphine/borane terminatedpoly(silole co germole) for the evaluation of luminescent polymer light emitting diode
New rac-XP(O)(OC6H5)(NHC6H4-p-CH3) [X = N(CH3)(cyclo-C6H11) and NH(C3H5)] and rac-(C6H5CH2NH)-P(O)(OC6H5)(NH-cyclo-C6H11) mixed-amide phosphinates
The mixed-amide phosphinates, rac-phenyl (N-methylcyclohexylamido)(p-tolylamido)phosphinate, C20H27N2O2P, (I), and rac-phenyl (allylamido)(p-tolylamido)phosphinate, C16H19N2O2P, (II), were synthesized from the racemic phosphorus–chlorine compound (R...
Aminophosphine Palladium(0) Complex Supported on ZrO2 Nanoparticles (ZrO2@AEPH2-PPh2-Pd(0)) as an Efficient Heterogeneous Catalyst for Suzuki–Miyaura and Heck–Mizoroki Reactions in Green Media
A new aminophosphine palladium(0) complex
supported on ZrO2 nanoparticles (ZrO2@AEPH2-PPh2-
Pd(0)) was successfully synthesized and characterized
using FT-IR, XRD, XPS, SEM, TEM, EDS, TGA and ...